Enantioselective reduction of ketones and imines catalyzed by (CN-box)Re(V)-oxo complexes.
نویسندگان
چکیده
The development and application of chiral, non-racemic Re(V)-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.
منابع مشابه
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عنوان ژورنال:
- Chemistry
دوره 16 31 شماره
صفحات -
تاریخ انتشار 2010